Chemistry & Chemical Biology / New Brunswick

Faculty and Staff

Directory of People



View: All | Faculty | Administrative | Department Staff
Grad Students | Instructional Staff | Retired Faculty
Research Professors | Post-Docs | Research Staff



Kai Hultzsch
Assistant Professor
Email



 

Contact

 

Links

Phone: (732) 445-1785
Fax: (732) 445-5312
Lab: (732) 445-????
Dept: (732) 445-2618

Office: WL-A102
Mail: Chemistry & Chemical Biology, 610 Taylor Road, Piscataway, NJ 08854

Research Summary

Synthesis of chiral organometallic complexes, with special emphasis on rare earth metals. The complexes are applied as catalysts in stereoselective and enantioselective small molecule syntheses (e. g. hydroamination, hydrophosphination, hydrosilylation, hydrogenation), as well as catalysts for the stereospecific (co)polymerization of nonpolar and polar monomers or epoxide/carbon dioxide copolymerization.

Curriculum Vitae


Awards & Honors


Representative Publications


  1. "Synthesis and Characterization of New Biphenolate and Binaphtholate Rare Earth Metal Amido Complexes. Catalysts for Asymmetric Olefin Hydroamination/Cyclization." Gribkov, D. V.; Hultzsch, K. C.; Hampel, F. Chem. Eur. J. 2003, 9, 4796-4810.
  2. "Kinetic resolution of chiral aminoalkenes via asymmetric hydroamination/cyclisation using binaphtholate yttrium complexes" Gribkov, D. V.; Hultzsch, K. C. Chem. Commun. 2004, 730-731.
  3. "New Yttrium Complexes Bearing Diamidoamine Ligands as Efficient and Diastereoselective Catalysts for the Intramolecular Hydroamination of Alkenes and Alkynes" Hultzsch, K. C.; Hampel, F.; Wagner, T. Organometallics 2004, 23, 2601-2612.
  4. "Hydroamination/Cyclization of Aminoalkenes Using Cationic Zirconocene and Titanocene Catalysts" Gribkov, D. V.; Hultzsch, K. C. Angew. Chem. Int. Ed. 2004, 44, 5542-5546; Angew. Chem. 2004, 116, 5659-5663.
  5. "Transition Metal-Catalyzed Asymmetric Hydroamination of Alkenes (AHA)" Hultzsch, K. C.; Adv. Synth. Catal., 2005, 347, 367-391.
  6. "Catalytic asymmetric hydroamination of non-activated olefins" Hultzsch, K. C. Org. Biomol. Chem. 2005, 3, 1819-1824.
    This work was featured on the front cover of Organic Biomolecular Chemistry (Volume 3, Issue no. 10, May 21st 2005).
  7. "Rare Earth Metal Complexes Based on b-Diketiminato and Novel Linked Bis(b-Diketiminato) Ligands: Synthesis, Structural Characterization and Catalytic Application in Epoxide/CO2-Copolymerization." Vitanova, D. V.; Hampel, F.; Hultzsch, K. C. J. Organomet. Chem., 2005, 690, 5182-5197.
  8. "3,3’-Bis(trisarylsilyl)-Substituted Binaphtholate Rare Earth Metal Catalysts for Asymmetric Hydroamination" Gribkov, D. V.; Hultzsch, K. C.; Hampel, F. J. Am. Chem. Soc. 2006, 128, 3748-3759.
  9. "Base catalysed asymmetric hydroamination/cyclisation of aminoalkenes utilising a chiral dimeric diamidobinaphthyl dilithium salt" Horrillo Martínez, P.; Hultzsch, K. C.; Hampel, F. Chem. Commun. 2006, 2221-2223.
    This work was featured on the inside front cover of Chemical Communications (Issue no. 21, June 4th 2006).



Interested in Graduate Study at Rutgers University?

Find out more about the Rutgers Graduate program and fill out an online application.