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Chemistry & Chemical Biology / New Brunswick

Research

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Surface chemistry: chlorine induced copper-silicide crystallization on silicon

A 1300 x 1300Å STM Scanning Tunnelling Microscopy image of an atom-thick Cu2Si layer on a single crystal Si(111) surface. Following chlorine exposure and annealing at ~450°C  SiCl2 and SiCl4 desorption, together with large scale copper migration, has given rise to the fine scale roughness as well as larger (nanoscale) crystallites.  A chlorine coverage of ~0.5ML remains.  The associated research project centers on Cu catalyzed, Cl and CH3 etching of Si, for large scale (CH3)2Cl2Si (g) production.
The latter commercial process is essential in fabrication of all silicone materials.

For more information visit Jane Hinch's website.




Select from any of the following topics to learn more about the department's research in that area.

The First Semiconductor Bulk Material That Emits Direct White Light

Electropositive Chalcogen Encapsulants of Oxo Cluster Compounds

Alkane metathesis

Lanthanide Fluoride Clusters: the most efficient molecular NIR emission sources currently available

Phenylalanine

Amyloidogenesis in vitro

Protein Data Bank

Structure of Transcription Initiation Complexes

DNA structure and interactions

Surface chemistry: chlorine induced copper-silicide crystallization on silicon

Transition structure for the enzyme-catalyzed decarboxylation of a nucleic acid